The OIP-UV is a tool for mapping light non-aqueous phase liquids (LNAPL), residual LNAPL, and light oils. The OIP-UV system utilizes a 275nm ultraviolet (UV) light emitting diode (LED) to produce fluorescence from the polycyclic aromatic hydrocarbons (PAHs) contained in fuels and light oils. The UV light is directed out a sapphire window in the side of the probe onto the soil. When LNAPL level fuels are present, the PAH molecules will absorb the UV light energy and shortly afterwards emit a light photon (fluorophore) which is the resultant fluorescence. Directly behind the sapphire window, the onboard camera captures images of the soil and any fluorescence produced by hydrocarbon contaminants present. The acquisition software analyzes each pixel of the images taken for the presence of color typical of fuel fluorescence. If there is no fuel present in the formation, or it is not in high enough concentration, then the returned camera image will appear black or dark under the UV light source. The OIP acquisition software logs percent area fluorescence with depth. The OIP-UV probe contains a visible as well as UV LEDs. The visible images are useful for determination of soil color, texture and occasionally confirming the presence of fuel or oil LNAPL globules.
The OIP is advanced approximately 3 feet per minute.
The OIP software does not automatically provide any distinct product designation based upon the fluorescence image returned from the oil. Each fuel or oil type may give a slightly different coloration of the respondent fluorescent image. Assuming that the coloration of the QA diesel and motor oil images are consistent throughout the project, if the coloration of the fuel fluorescence has changes in the borehole or between logs then the different is likely due to either different levels of weathering of the same fuel/oil product or there are two separate fuel/oils present.
No concentration can not be determined. OIP Fluorescence only occurs when fuel or oil NAPL or residual NAPL is present. The higher the % fluorescence response the greater the distribution of fuel NAPL.
No chlorinated DNAPL solvents will not fluoresce on their own without help from something else. Many chlorinated solvents like Trichloroethylene and Trichloroethane have been used as degreaser in industrial manufacturers. In this case there is a likelihood that the comingled oils and greases within the DNAPL will fluorescence under the OIP-UV excitation. We recommend a sample being collected and tested prior to mobilization for this purpose. Also, MIP can be used the track the chlorinated solvent plume from DNAPL to sub ppm levels.